The seasonal variation of streamwater chemistry in three forested Mediterranean catchments

Streamwater chemistry is described for three streams draining undisturbed, evergreen broad-leaved forested catchments on phyllites in NE Spain: two streams with no or negligible flow in summer are located in the Prades massif, and one perennial stream is in the wetter Montseny mountains. Weekly data for a study period of 2–4 years are provided to (1) describe the seasonal variations in streamwater chemistry, (2) analyse the relationship between stream discharge and solute concentrations using a two-component mixing model and (3) search for patterns of temporal variation in stream solute concentrations after discounting the effects of discharge. At Prades, concentrations of all analysed ions, except NO⁻₃, showed marked seasonal variations in stream water, whereas at Montseny only ions related to mineral weathering (HCO⁻₃, Na⁺, Ca²⁺ and Mg²⁺) showed strong seasonality. Ion concentrations were more closely dependent on instantaneous discharge at Montseny than at Prades. The residuals of the relationship between solute concentrations and discharge retained a strong seasonality at Prades, but not at Montseny. These differences are related to the major hydrochemical processes that determine the streamwater chemistry at each site. The same processes are probably operative in the three catchments, but are of varying relative importance. At Montseny, the mixing of waters of different chemical composition seems to be the major process controlling streamwater chemistry, although the soilwater end-member composition predicted by the mixing model applied did not match the measured soilwater chemistry. In the drier Prades catchments, the two major hydrochemical processes determining the seasonal variation of streamwater chemistry are (1) the restart of flow after the summer drought, which flushes out the solutes accumulated during the dry period, and (2) the seasonal changes in groundwater chemistry that result from the interplay of water residence time, temperature and CO₂ partial pressure. In Mediterranean catchments with relatively high precipitation, such as Montseny, the seasonal variation in the streamwater chemistry is largely determined by the same processes as at humid-temperate sites, whereas in drier Mediterranean catchments, such as Prades, the major hydrochemical processes are clearly distinct.     

Stable hydrogen and oxygen isotope studies of rainfall and streamwaters for two contrasting holm oak areas of Catalonia, northeastern Spain

Results are presented of a study of stable hydrogen and oxygen isotopes in rainfall and streamwaters for the Montseny and Prades areas in northeastern Spain: results cover the full year of 1991. The isotopic pattern for rainfall is similar for both areas: there is a wide range in isotopic contents and the results show a strong, near-linear trend, δ²H = 7.9 × δ¹⁸O + 9.8 (N = 59; r² = 0.952), the ‘local meteoric line’. There is slight curvature to the data which may be related to the sources of water vapour forming the rainfall. Within the streams, the isotopic variability is much less than that of the rainfall although the data lie on, or very near to, the meteoric line. Data for detailed collections during storm events show more scatter than those collected regularly on a fortnightly basis. The event data show a linear feature that conforms to the local meteoric line. These results indicate that: (1) the main supply of water to the stream stormflow comes from water stored in the catchment prior to the event; (2) waters of more than one isotopic composition reside within the catchment and are transferable to the stream during storm events; (3) the main process of water transfer from the catchment back to the atmosphere comes from transpiration by the trees and (possibly) complete evaporation from the near-surface soil horizons and the tree canopy; (4) the isotopic technique cannot be used for quantitative hydrograph separation in this instance — at least two water types can be present within the catchment at any given time.     

Nonlinearities, Feedbacks and Critical Thresholds within the Earth's Climate System

The Earth's climate system is highly nonlinear: inputs and outputs are not proportional, change is often episodic and abrupt, rather than slow and gradual, and multiple equilibria are the norm. While this is widely accepted, there is a relatively poor understanding of the different types of nonlinearities, how they manifest under various conditions, and whether they reflect a climate system driven by astronomical forcings, by internal feedbacks, or by a combination of both. In this paper, after a brief tutorial on the basics of climate nonlinearity, we provide a number of illustrative examples and highlight key mechanisms that give rise to nonlinear behavior, address scale and methodological issues, suggest a robust alternative to prediction that is based on using integrated assessments within the framework of vulnerability studies and, lastly, recommend a number of research priorities and the establishment of education programs in Earth Systems Science. It is imperative that the Earth's climate system research community embraces this nonlinear paradigm if we are to move forward in the assessment of the human influence on climate.     

Carbon-rich chondritic clast PV1 from the Plainview H-chondrite regolith breccia: Formation from H3 chondrite material by possible cometary impact

Chondritic clast PV1 from the Plainview H-chondrite regolith breccia is a subrounded, 5-mm-diameter unequilibrated chondritic fragment that contains 13 wt% C occurring mainly within irregularly shaped 30-400-μm-size opaque patches. The clast formed from H3 chondrite material as indicated by the mean apparent chondrule diameter (310 μm vs. ∼300 μm in H3 chondrites), the mean Mg-normalized refractory lithophile abundance ratio (1.00 ± 0.09×H), the previously determined O-isotopic composition (Δ¹⁷O = 0.66‰ vs. 0.68 ± 0.04‰ in H3 chondrites and 0.73 ± 0.09‰ in H4-6 chondrites), the heterogeneous olivine compositions in grain cores (with a minimum range of Fa1-19), and the presence of glass in some chondrules. Although the clast lacks the fine-grained, ferroan silicate matrix material present in type 3 ordinary chondrites, PV1 contains objects that appear to be recrystallized clumps of matrix material. Similarly, the apparent dearth of radial pyroxene and cryptocrystalline chondrules in PV1 is accounted for by the presence of some recrystallized fragments of these chondrule textural types. All of the chondrules in PV1 are interfused indicating that temperatures must have briefly reached ∼1100°C (the approximate solidus temperature of H-chondrite silicate). The most likely source of this heating was by an impact. Some metal was lost during impact heating as indicated by the moderately low abundance of metallic Fe-Ni in PV1 (∼14 wt%) compared to that in mean H chondrites (∼18 wt%). The carbon enrichment of the clast may have resulted from a second impact event, one involving a cometary projectile, possibly a Jupiter-family comet. As the clast cooled, it experienced hydrothermal alteration at low water/rock ratios as evidenced by the thick rims of ferroan olivine around low-FeO olivine cores. The C-rich chondritic clast was later incorporated into the H-chondrite parent-body regolith and extensively fractured and faulted.     

Fault-slip, bed-length and area variations in experimental rollover anticlines over listric normal faults: influence in extension and depth to detachment estimations

To check the behaviour of physical experiments of simple rollover anticlines over listric normal faults, several fault-slip, bed-length and area parameters are measured for different beds in two stages of evolution of two physical experiments. Given a certain amount of extension, the heave and dip of the displacement vary for different beds, whereas the throw is approximately constant for small amounts of extension and the displacement remains constant for high amounts of extension. Neither bed lengths nor areas beneath beds remain constant with increasing extension. A number of techniques allow amounts of extension and detachment depth to be estimated given one or more marker horizons, the portion of the fault between hanging-wall and footwall cut off points, the depth to detachment and/or the shear angle. These techniques are applied to the physical experiments of listric normal faults analysed. Since many of these techniques rely on parameters measured on the physical experiments such as fault slip, bed length and area, the influence of these parameters on the different magnitudes of extension and detachment depths estimated using different techniques is discussed and the accuracy of the results is compared.     

Tilting neotectonics of the Guadiamar drainage basin,SW Spain

The Guadiamar river ?ows from the southern Iberian Massif to the Guadalquivir foreland basin, SW Spain. Its drainage basin displays asymmetries in the stream network, the arrangement of alluvial terraces and the con?guration of the trunk river valley. The stream network asymmetry was studied using morphometric measures of transverse topographic sym‐metry, asymmetry factor and drainage basin shape. The alluvial terraces were studied through the lithologic logs of more than a hundred boreholes and ?eld mapping. The morphometric methods demonstrate a regional tectonic tilting toward the SSE, causing both the migration of the Guadiamar river toward the east and the migration of the Guadiamar tributaries toward the southwest. As a consequence of the Guadiamar river migration, an asymmetric valley developed, with a steep eastern margin caused by river dissection, and a gentle western margin where the main alluvial deposits are found. The ages obtained using the ¹⁴C analysis of samples from several alluvial deposits show that the river migration, and thus tilting, has occurred during the Holocene as well as earlier in the Quaternary. This interpretation revises the Guadiamar longitudinal fault assumed by previous studies. Copyright © 2003 John Wiley & Sons, Ltd.     

Reverse modelling of detachment folds; application to the Pico del Aguila anticline in the South Central Pyrenees (Spain)

A simple method to estimate fold-amplification and thrust-movement rates for detachment folds is documented and illustrated by its application to a symmetrical detachment fold in the Southern Pyrenees, Spain. The technique provides a complete record of the kinematic evolution of detachment folds and is based on the application of equations for detachment folds involving limb rotation. The method uses the stratal pattern of the syntectonic sediments and assumes that these growth strata were deposited horizontally, that the folds involve a homogeneous competent unit detached over a ductile horizon, and that the folds can be represented by chevronkink bands. The procedure is applicable to any detachment fold with associated growth strata that display wedge geometries (‘progressive unconformities’) indicating limb rotation through time. This method can be used for both detachment folds formed with constant limb length or variable limb length, and it can also accommodate undecompacted or decompacted growth strata.